首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   58642篇
  免费   6176篇
  国内免费   4239篇
化学   23515篇
晶体学   240篇
力学   4337篇
综合类   1222篇
数学   19922篇
物理学   19821篇
  2023年   572篇
  2022年   791篇
  2021年   1683篇
  2020年   1340篇
  2019年   1427篇
  2018年   1171篇
  2017年   1471篇
  2016年   1762篇
  2015年   1684篇
  2014年   2571篇
  2013年   3844篇
  2012年   2741篇
  2011年   3370篇
  2010年   3094篇
  2009年   3704篇
  2008年   3960篇
  2007年   4230篇
  2006年   3250篇
  2005年   2477篇
  2004年   2391篇
  2003年   2208篇
  2002年   2058篇
  2001年   1840篇
  2000年   1456篇
  1999年   1309篇
  1998年   1212篇
  1997年   993篇
  1996年   963篇
  1995年   903篇
  1994年   740篇
  1993年   731篇
  1992年   699篇
  1991年   571篇
  1990年   410篇
  1989年   298篇
  1988年   363篇
  1987年   286篇
  1986年   297篇
  1985年   404篇
  1984年   301篇
  1983年   189篇
  1982年   344篇
  1981年   526篇
  1980年   460篇
  1979年   505篇
  1978年   401篇
  1977年   302篇
  1976年   255篇
  1974年   91篇
  1973年   159篇
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
41.
42.
In this paper, we study the following Klein–Gordon–Maxwell system Δu+(λa(x)+1)u(2ω+ϕ)ϕu=f(x,u),inR3,Δϕ=(ω+ϕ)u2,inR3.Using variational methods, we obtain the existence of ground state solutions under some appropriate assumptions on a and f.  相似文献   
43.
The electrochemical behavior of austenitic stainless steel (Type 304) in 3 M sulfuric acid with 3.5% recrystallized sodium chloride at specific concentrations of butan-1-ol was investigated with the aid of potentiodynamic polarization, open circuit measurement and weight loss technique. Butan-1-ol effectively inhibited the steel corrosion with a maximum inhibition efficiency of 78.7% from weight-loss analysis and 80.9% from potentiodynamic polarization test at highest concentration studied. Adsorption of the compound obeyed the Freundlich isotherm. Thermodynamic calculations reveal physiochemical interactions and spontaneous adsorption mechanism. Surface characterizations showed the absence of corrosion products and topographic modifications of the steel. Statistical analysis depicts the overwhelming influence and statistical significance of inhibitor concentration on the inhibition performance.  相似文献   
44.
A panel of six new arene Ru (II)‐NHC complexes 2a‐f , (NHC = 1,3‐diethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1a , 1,3‐dicyclohexylmethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1b and 1,3‐dibenzyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1c ) were synthesized from the transmetallation reaction of Ag‐NHC with [(η6‐arene)RuCl2]2 and characterized. The ruthenium (II)‐NHC complexes 2a‐f were developed as effective catalysts for α‐alkylation of ketones and synthesis of bioactive quinoline using primary/amino alcohols as coupling partners respectively. The reactions were performed with 0.5 mol% catalyst load in 8 h under aerobic condition and the maximum yield was up to 96%. Besides, the different alkyl wingtips on NHC and arene moieties were studied to differentiate the catalytic robustness of the complexes in the transformations.  相似文献   
45.
The gravitational Szekeres differential system is completely integrable with two rational first integrals and an additional analytical first integral. We describe the dynamics of the Szekeres system when one of these two rational first integrals is negative, showing that all the orbits come from the infinity of R4 and go to infinity.  相似文献   
46.
The aim of this work is to derive an accurate model of two-dimensional switched control heating system from data generated by a Finite Element solver. The nonintrusive approach should be able to capture both temperature fields, dynamics and the underlying switching control rule. To achieve this goal, the algorithm proposed in this paper will make use of three main ingredients: proper orthogonal decomposition (POD), dynamic mode decomposition (DMD) and artificial neural networks (ANN). Some numerical results will be presented and compared to the high-fidelity numerical solutions to demonstrate the capability of the method to reproduce the dynamics.  相似文献   
47.
We consider a Schrödinger operator L=?d2/dx2+V(x) on R, where V is a real-valued measurable function, and give an explicit and simple characterization of intrinsic ultracontractivity (IU) of the Schrödinger semigroup generated by L for a wide class of potentials. By making use of it, we also give new examples of potentials for which the semigroups satisfy (IU) or non-(IU).  相似文献   
48.
Oxidative dehydrogenation (ODH) of n-octane was carried out over a vanadium–magnesium oxide catalyst in a continuous flow fixed bed reactor. The catalyst was characterized by ICP–OES, powder XRD and SEM. The catalytic tests were carried out at different gas hourly space velocities (GHSVs), viz. 4000, 6000, 8000, and 10,000 h?1. The best selectivity for octenes was obtained at the GHSV of 8000 h?1, while that for C8 aromatics was attained at the GHSV of 6000 h?1 at high temperatures (500 and 550 °C). The catalytic testing at the GHSV of 10,000 h?1 showed the lowest activity, while that at the GHSV of 4000 h?1 consistently showed the lowest ODH selectivity. Generally, the best ODH performance was obtained by the catalytic testing at the GHSVs of 6000 and 8000 h?1. No phasic changes were observed after the catalytic testing.  相似文献   
49.
50.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号